Effects of graphene oxides on the cure behaviors of a tetrafunctional epoxy resin
نویسندگان
چکیده
The influence of graphene oxides (GOs) on the cure behavior and thermal stability of a tetrafunctional tetraglycidyl-4,4’-diaminodiphenylmethane cured with 4,4’-diaminodiphenylsulfone was investigated by using dynamic differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). The dynamic DSC results showed that the initial reaction temperature and exothermal peak temperature decreased with the increase of GO contents. Furthermore, the addition of GO increased the enthalpy of epoxy cure reaction. Results from activation energy method showed that activation energies of GO/epoxy nanocomposites greatly decreased with the GO content in the latter stage, indicating that GOs significantly hindered the occurrence of vitrification. The oxygen functionalities, such as hydroxyl and carboxyl groups, on the surface of GOs acted as catalysts and facilitated the curing reaction and the catalytic effect increased with the GO contents. TGA results revealed that the addition of GOs decreased the thermal stability of epoxy.
منابع مشابه
High-performance starch-modified graphene oxide/epoxy nanocomposite coatings: A glimpse at cure kinetics and fracture behavior
Epoxy is a versatile resin used in different fields such as coatings, colors, colorants, and composites. Adding nano-scale fillers/additives to the epoxy has valued epoxy coatings for engineering applications, and opened the time of advanced epoxy-based nanocomposite coatings. In the present work, graphene oxide GO was chemically functionalized with starch, as a natural polymer, and added to th...
متن کاملEffect of Graphene Oxide Decorated With Synthesized Nano-CeO2 on Barrier Properties of Epoxy Anticorrosion Coatings
In this paper, graphene oxide decorated with cerium oxide (CeO2) nanoparticles was prepared and used as anticorrosive pigments in epoxy nanocomposite coatings. The synthesized nanoparticle was characterized by FTIR, XRD, SEM, and EDX analyses. Graphene oxide decorated with CeO2 nanoparticles was dispersed in epoxy resin by sonication. The optimum nanoparticle content of th...
متن کاملInvestigating the Effect of Modifier Chain Length on Insulation Properties of Polysulfide Modified Epoxy Resin
Polysulfide resins,with trade name of G4 and G112, with short and long chain lengths respectively, were used as reactive modifiers to toughen epoxy resin. The effects of molecular weights of G4 and G112 on impact resistance, dielectric constant, thermal conductivity as well as decomposition heat and adhesion properties of toughened epoxy were investigated. The impact strength and the diel...
متن کاملThe Modification of a Tetrafunctional Epoxy and Its Curing Reaction
Recent experimental results showed that the Tg of cured resin scarcely decreased and the impact strength of resins increased by over 50% when a tetrafunctional epoxy named N,N,N',N'-tetraglycidyl-4,4'-diaminodiphenyl ether (TGDDE) was introduced to an appropriate flexible chain from a dimer fatty acid (DFA). In order to understand the reason for this phenomenon, the modification and the chemica...
متن کاملThe Effect of Epoxy-Polysulfide Copolymer Curing Methods on Mechanical-Dynamical and Morphological Properties
Epoxy – Polysulfide copolymers without or with low amounts of epoxy in their structure have poor mechanical properties in oxidative curing system.To strengthen the mechanical properties of polysulfide elastomer inclusion of epoxy resin (Epon828) as hard segment was studied. FT-IR spectroscopy and rheometry were used to verify the formation of epoxy-polysulfide copolymer. Results obtained f...
متن کامل